Valach F., Ondracek J., Melnik M. Crystallographic Statistics in Chemical Physics: An Approach to Statistical Evaluation of Internuclear Distances in Transition Element Compounds (Inorganic Chemistry Concepts. Volume 12)

Springer-Verlag, Berlin, Heidelberg, 1988. — 194 p. — ISBN: 366201601XThis book introduces the concept of crystallographic non- rigidity and asymmetry of the transition elements as central atoms organometallic compounds. This intrinsic behavior of central atoms in condensed matter is quantified by applying statistical approach. Averaging of extrinsic factors in crystal structures is tested by using variance analysis. Introduction of the above mentioned concept and applications of variance analysis as an approximation for considering factors influencing properties of central atom in the crystal is original and new.Statistics of Interatomic Distances
Factors Influencing the Dispersion of Lengths of Interatomic Vectors
Statistics of Crystallographic Sites of Central Monatomic Entities
Statistics of Bond Distances Between Central Monatomic Entities and Ligands
Conclusions
Chemical Abbreviatious
Appendixes