Springer International Publishing, Switzerland, 2016. — 1053 p. — ISBN: 3319318659
Contributions featuring the chemistry and applications of a family of macrocyclic compounds collectively known as 'calixarenes' are presented in this edited volume. The arsenal of structures based on calixarenes provides tools which are effective in numerous areas of supramolecular chemistry. The Editors have compiled a timely volume which contains up to date, high calibre contributions from a large number of international authors. A broad perspective on the progress and future of calixarene chemistry is presented. Aimed at students and researchers active in Supramolecular Chemistry.
From the ContentsIntroduction and History
Chiral Calixarenes and Resorcinarenes
Preparation of Methylene-Substituted Calixarenes
Calixarene: from Capsules to Polymers
Calixazacryptand-Based Receptors
Large Calixarenes
Resorcarenes as Preorganized Synthons for Surface Recognition and Host-Guest Chemistry
A Chronology of Cavitands
Calixarenes and Resorcinarenes Bridged at the Wider Rim
Functionalized Calixpyrroles: Building Blocks for Self-Assembly
Thiacalixarenes
Azacalixaromatics
Oxacalixarenes
Homoheteracalix arenes (X ¼ S, Se, N)
Functionalization and Properties of Homooxacalixarenes
Triptycene-Derived Calixarenes, Heteracalixarenes and Analogues
Pillararenes: Easy-to-Make Pillar-Shaped Macrocyclic Hosts for Supramolecular Chemistr
Function-Directed Supramolecular Assembly Based on Water Soluble Calixarenes
Water-Soluble Cryptophanes: Design and Properties
Calixsugars: Finally Reaching Their Therapeutic Potential?
New Technologies Powered by Protein-Binding Calixarenes
Calixarenes and Nucleic Acids
Structural Trends in Calixarene-Supported Cluster Chemistry
Calixarenes as Supramolecular Catalysts Endowed with Esterase and Phosphodiesterase Activity
Calixarenes in Organo and Biomimetic Catalysis
Fluorescent Calixarene Hosts
Calixarene Threading by Viologen-Based Axles
Calixarene Threading via Superweak Anion
Hydrogen Bond Hexameric Capsules: Structures, Host-Guest Interactions, Guest Affinities, and Catalysis
Self-Assembled Dimeric Containers Based on Calixarene, Resorcinarene and Calixpyrrole Scaffolds
Calixarenes and Fullerenes
Calixarene-Encapsulated Nanoparticles: Synthesis, Stabilization, and Self-Assembly
Calixarenes and Nanoparticles
Calixarenes and Pillarenes on Surfaces
Calixarenes and Resorcinarenes at Interfaces
Solid State Features of Calixarenes
Gas Sorption and Storage Properties of Calixarenes